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F17 starting/stop service: "Error: No space left on device"

I've been seeing this many times. What space is it complaining about?

# systemctl stop postfix.service
Error: No space left on device
# systemctl start postfix.service
Error: No space left on device

Job failed. See system journal and 'systemctl status' for details.

# systemctl status postfix.service
postfix.service - Postfix Mail Transport Agent
      Loaded: loaded (/usr/lib/systemd/system/postfix.service; enabled)
      Active: failed (Result: timeout) since Mon, 17 Dec 2012 13:52:06 -0800; 1min 45s ago
     Process: 10471 ExecStop=/usr/sbin/postfix stop (code=exited, status=0/SUCCESS)
     Process: 10518 ExecStart=/usr/sbin/postfix start (code=exited, status=0/SUCCESS)
     Process: 10515 ExecStartPre=/usr/libexec/postfix/chroot-update (code=exited, status=1/FAILURE)
     Process: 10510 ExecStartPre=/usr/libexec/postfix/aliasesdb (code=exited, status=0/SUCCESS)
    Main PID: 10212 (code=killed, signal=TERM)
      CGroup: name=systemd:/system/postfix.service

Dec 17 13:50:37 fong.homelinux.com postfix/postfix-script[10590]: starting the Postfix mail system
Dec 17 13:50:37 fonghome.homelinux.com postfix/master[10591]: daemon started -- version 2.9.4, configuration /...fi

# df -h
Filesystem                   Size  Used Avail Use% Mounted on
devtmpfs                     3.9G  8.0K  3.9G   1% /dev
tmpfs                        3.9G  2.6M  3.9G   1% /dev/shm
tmpfs                        3.9G  2.5M  3.9G   1% /run
/dev/mapper/vg_fong-lv_root   50G  7.6G   42G  16% /
tmpfs                        3.9G     0  3.9G   0% /sys/fs/cgroup
tmpfs                        3.9G     0  3.9G   0% /media
/dev/sdc1                    111G   46G   59G  44% /ssd1
/dev/sda2                    485M   98M  362M  22% /boot
/dev/md127                   1.8T  1.3T  511G  71% /d

Works fine when starting postfix manually:

# postfix start
postfix/postfix-script: starting the Postfix mail system

I've seen this with a couple of services, not just postfix.

F17 starting/stop service: "Error: No space left on device"

I've been seeing this many times. What space is it complaining about?

# systemctl stop postfix.service
Error: No space left on device
# systemctl start postfix.service
Error: No space left on device

Job failed. See system journal and 'systemctl status' for details.

# systemctl status postfix.service
postfix.service - Postfix Mail Transport Agent
      Loaded: loaded (/usr/lib/systemd/system/postfix.service; enabled)
      Active: failed (Result: timeout) since Mon, 17 Dec 2012 13:52:06 -0800; 1min 45s ago
     Process: 10471 ExecStop=/usr/sbin/postfix stop (code=exited, status=0/SUCCESS)
     Process: 10518 ExecStart=/usr/sbin/postfix start (code=exited, status=0/SUCCESS)
     Process: 10515 ExecStartPre=/usr/libexec/postfix/chroot-update (code=exited, status=1/FAILURE)
     Process: 10510 ExecStartPre=/usr/libexec/postfix/aliasesdb (code=exited, status=0/SUCCESS)
    Main PID: 10212 (code=killed, signal=TERM)
      CGroup: name=systemd:/system/postfix.service

Dec 17 13:50:37 fong.homelinux.com postfix/postfix-script[10590]: starting the Postfix mail system
Dec 17 13:50:37 fonghome.homelinux.com postfix/master[10591]: daemon started -- version 2.9.4, configuration /...fi

# df -h
Filesystem                   Size  Used Avail Use% Mounted on
devtmpfs                     3.9G  8.0K  3.9G   1% /dev
tmpfs                        3.9G  2.6M  3.9G   1% /dev/shm
tmpfs                        3.9G  2.5M  3.9G   1% /run
/dev/mapper/vg_fong-lv_root   50G  7.6G   42G  16% /
tmpfs                        3.9G     0  3.9G   0% /sys/fs/cgroup
tmpfs                        3.9G     0  3.9G   0% /media
/dev/sdc1                    111G   46G   59G  44% /ssd1
/dev/sda2                    485M   98M  362M  22% /boot
/dev/md127                   1.8T  1.3T  511G  71% /d

Works fine when starting postfix manually:

# postfix start
postfix/postfix-script: starting the Postfix mail system

I've seen this with a couple of services, not just postfix.